Angelina Jolie officially called it quits with Brad Pitt on Monday, putting an end to their two-year marriage and 12-year relationship. This not only marks the dissolution of their family of eight – consisting of their children Maddox (15), Pax (12), Zahara (11), Shiloh (10), and twins Vivienne and Knox (8) – but also the end of an era known as Brangelina, the ultimate power couple on the red carpet. Together, they effortlessly commanded attention and dominated every red carpet appearance, earning themselves the title of King and Queen of the Carpet.

The debut appearance of Angelina Jolie and Brad Pitt as a couple happened during the glamorous Mr And Mrs Smith premiere in Los Angeles in June 2005. They attempted to maintain a relaxed demeanor on the red carpet.

No Public Display of Affection: The celebrities refrained from any public displays of affection at the Tokyo premiere of Mr And Mrs Smith in November 2005. They were hesitant to hold hands or even wrap an arm around each other.
Their initial public appearance as a couple took place at the ShoWest 20th Century Fox Luncheon in March 2005 at the Paris Hotel in Las Vegas. The purpose of this event was to promote their film, Mr And Mrs Smith.
However, it was not until June 2005 that they walked their first red carpet together at the movie’s premiere in Los Angeles. Despite ongoing rumors and speculation, Pitt, who was going through a divorce with Jennifer Aniston at the time, did not openly confirm his relationship with Jolie.

Their inaugural appearance as a duo on the red carpet occurred twelve years ago in December 2006. The occasion was the highly anticipated premiere of her cinematic masterpiece, The Good Shepherd, which took place in the bustling city of New York. Dressed to impress, the dynamic couple exuded an air of elegance and sophistication, both opting for the timeless allure of black attire.

PDA observation: In January 2007, they made their debut as a couple at the esteemed Golden Globe Awards. Angie opted for a glamorous sleeveless gown and a timeless updo, exuding elegance. Throughout the evening, they embraced affectionately and exchanged adoring gazes.

Her moment to sparkle: During the Cannes premiere of Mighty Heart in May 2007, they graced the red carpet together, catching the attention of many. However, it wasn’t until over a year later that they reunited for their next public appearance.
Fast forward to December 2006, when both of them donned stylish black attire for the premiere of her movie, The Good Shepherd, in New York. Looking elegant and sophisticated, they made a striking duo.
In January 2007, they made their debut as a couple at the Golden Globe Awards. Angie opted for an elegant sleeveless gown and a timeless updo, while they exchanged warm embraces and affectionate glances throughout the event.

Princess Jolie: The world was captivated when his movie Ocean’s Thirteen premiered in Cannes a few days later.

Head Over Heels: The Hottest Guy on Earth couldn’t resist showing affection to his lady love.

Tender and affectionate: She was dressed in a stunning yellow dress that perfectly resembled Belle from the enchanting tale of Beauty and the Beast. During the Cannes premiere of Mighty Heart in May 2007, they were spotted together, creating a buzz amongst onlookers. However, it was their appearance at the premiere of his film Ocean’s Thirteen a few days later that truly mesmerized the world. Sporting the same gorgeous yellow gown that evoked Belle’s elegance, she captured attention, while he gently placed his hand on her lower back and she playfully intertwined her arm with his.

Dressed to impress: Hollywood’s elite solidified their status as a power couple, capturing all attention at the illustrious 64th Venice Film Festival held in September 2007. Donning an exquisite lace gown, she radiated elegance, while he exuded sheer sophistication in a pristine white tux jacket. Together, they embraced their regal reputation, leaving an indelible mark on the glamorous event.

The mesmerizing gaze of affection: The couple became famous for sharing tender looks in the public eye
In a subsequent event in Los Angeles, exactly one month after the initial movie premiere, he once again playfully touched her backside. Their status as Hollywood’s ultimate power couple was solidified at the 64th Venice Film Festival in September 2007. She stunned in a captivating black lace gown adorned with three elegant strands of pearls, while he exuded charm in a pristine white tuxedo jacket. Continuing their stylish appearances, during the London premiere of her film Beowulf in November 2007, she affectionately embraced him while showcasing a striking ensemble featuring leather slacks.

Infant on deck: During the January 2008 SAG awards in Los Angeles, Angelina proudly displayed her blossoming belly while Papa Pitt held her hand affectionately and planted a tender kiss on her cheek. This heartwarming moment captured the world’s attention as she carried the anticipation of welcoming twins Vivienne and Knox into their growing family.

Chubby lady: Jolie made quite an impression during the Cannes Film Festival premiere of Kung Fu Panda in May 2008.

She shed the extra pounds quickly: In December, she had slimmed down enough to accompany Brad at the premiere of his film, The Curious Case of Benjamin Button, in Los Angeles.
Angelina proudly displayed her baby bump at the SAG Awards in January 2008, and Brad lovingly held her hand and kissed her cheek. At this time, she was expecting twins, Vivienne and Knox.
Showing off her pregnant belly once again, the 52-year-old actress attended the Independent Spirit Awards in February 2008.
During the Cannes Film Festival in May 2008, Jolie was noticeably large as she attended the premiere of the film Kung Fu Panda.

Absolutely stunning… and head over heels: The talented actress, known for her portrayal of Gia, exuded sheer brilliance in a captivating shade of pink during the highly-anticipated film premiere of Inglourious Basterds. This unforgettable moment took place at the illustrious 62nd Cannes Film Festival, precisely in May 2009.

With their young child in tow, the couple attended the premiere of Invictus at the prestigious Academy of Motion Picture Arts and Sciences Theater in Beverly Hills in December 2009. As the year came to a close, Jolie had shed her post-baby weight and looked stunning as she accompanied Brad to his Curious Case of Benjamin Buttons premiere in LA. Their joint appearances at various awards shows and premieres continued to grab attention, as they exuded A-list glamour wherever they went. However, it was at the 81st Academy Awards in February 2009 that Jolie truly showcased her sophistication, when she unveiled her new jewelry collection with Robert Procop. The striking emerald green earrings she wore sparked a trend in the industry.

Fashion trailblazer: Jolie’s elegance reached new heights when she unveiled her exclusive collection of jewelry alongside Robert Procop at the 81st Academy Awards in 2009. The introduction of her mesmerizing emerald green earrings sparked a wave of admiration and set a new trend in motion.

The young woman from Los Angeles couldn’t adore her country boyfriend any more than she already did. In this particular moment, she appeared truly delighted by his presence.

During the January 2011 Golden Globe awards, he casually placed his hand on her backside, making quite a noticeable move.

Carpet Kiss: During the 64th annual Cannes Film Festival in May 2011, she opted for a stunning Versace ensemble, capturing everyone’s attention.
Their affectionate display continued at the premiere of Inglourious Basterds in May 2009, exuding an undeniable love. Brad maintained a classic tuxedo while Angelina donned a gentle pink gown, complemented by vibrant red lips.
In December 2010, while promoting The Tourist in New York City, Angelina exuded elegance in a stunning white Versace dress, perfectly complemented by Brad’s all-black attire.
Their impeccable fashion choices continued at the Tree Of Life premiere in Los Angeles in May 2011, where Angelina dazzled in a captivating all-red ensemble.
At this point in time, it seemed as if this power couple could do no wrong.

Uh-oh! It was time for Jolie’s inaugural blunder on the red carpet – during the Oscars in February 2012, she playfully showcased her slender leg from a sleek black dress without sleeves. This gesture resulted in humorous memes circulating online, creating a playful buzz for several weeks.

A more disheveled appearance for Brad: During the premiere of World War Z in June 2013, Pitt sported longer hair.
Following that, Jolie had her first mishap on the red carpet at the Oscars in February 2012. She playfully extended her slender leg out of her black sleeveless dress, resulting in weeks of online mockery through humorous memes.
Angelina took a hiatus from red carpet events until June 2013, when she attended the World War Z premiere in London alongside her sons, Maddox and Pax.
In February 2014, Jolie opted for a change, donning a woman’s tuxedo for the British Academy Awards. Brad decided to match her attire, although his shorter hair received criticism. It was cut short in preparation for his role in the WWII film Fury.

Improved beyond expectations: During the prestigious Oscars event held in March 2014, Jolie made a bold fashion statement by donning a transparent dress that elegantly highlighted her décolletage. This appearance came following her remarkable decision to undergo a preventive double mastectomy to mitigate the risk of developing breast cancer.

Hey pals! In the splendid month of April 2012, the twinkling stars adorned the sky and gracefully acknowledged their adoring fans with majestic waves.

Extending her hands gracefully, the enchanting model on the cover of Vogue reached out towards her beloved companion.

Overflowing with affection: With a radiant smile, the couple showcased their perfect match in London during the EE British Academy Film Awards held at The Royal Opera House in February 2014.
During the Oscars ceremony in March 2014, Jolie captivated the audience with a translucent gown that highlighted her décolletage.
What many were unaware of at the time was that she had already undergone a preventive double mastectomy in her battle against breast cancer.
Despite swirling rumors in the tabloids of a potential strain in their relationship, the couple’s appearance at the Maleficent premiere in Hollywood in May 2014 proved otherwise, as they exuded elegance in black attire while accompanied by their children.

The family: Despite rumblings in the media suggesting their relationship was in trouble, they appeared sophisticated and stylish in black attire during the Maleficent premiere in Hollywood in May 2014, attending with their children.

His beloved partner (dressed in leather): They appeared to be immensely content as he remained close by her throughout, offering unwavering support by clasping her hand continuously.
During the AFI Awards ceremony in January 2015, she opted for a stylish combination of slacks and a blazer, while he adopted a more casual look with a T-shirt and hat.
Their final public appearance together on the red carpet took place in November 2015 at the AFI Festival premiere of By The Sea in Los Angeles.

In a striking fashion choice, Jolie decided to deviate from tradition by opting for a blazer and slacks combination during her appearance at the 15th Annual AFI Awards held at Four Seasons Hotel in Beverly Hills back in January 2015.

Final instance: Their most recent joint presence on the red carpet transpired in November 2015, when they graced the AFI Festival premiere of By The Sea in Los Angeles.